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What is the pH of a solution made from 46.20 mL of a 0.0500 molar nitric acid solution diluted to 100.0 mL?

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What is the pH of a 0.25 M NH4Cl solution (Kb of NH3 = 1.76 ×\times 10-5)?

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As the pH decreases,the solubility of __________ would increase.


A) lead(II) chloride
B) silver iodate
C) calcium carbonate
D) mercury(I) bromide
E) silver chloride

F) B) and C)
G) B) and E)

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The degree of ionization of a weak acid __________ I.varies with the concentration of the acid. II.depends on the value of Ka. III.is 100%. IV.is greater than 50% but less than 100%.


A) I only
B) II only
C) III only
D) both I and II
E) IV only

F) D) and E)
G) C) and E)

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Which of the following would be the best choice for preparing a buffer with a pH = 5.0?


A) a solution of formic acid and sodium formate,Ka = 1.8 ×\times 10-4
B) a solution of acetic acid and sodium acetate,Ka = 1.8 ×\times 10-5
C) a solution of hypochlorous acid and sodium hypochlorite,Ka = 3.5 ×\times 10-8
D) a solution of boric acid and sodium borate,Ka = 5.8 ×\times 10-10
E) All of these solutions would be equally good choices for making this buffer.

F) A) and E)
G) D) and E)

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What reaction occurs as a hydrochloric acid solution is added to a solution containing equal concentrations of acetic acid and sodium acetate?


A) CH3COOH(aq) + H+(aq) \to CH3COOH2+(aq)
B) CH3COO-(aq) + H+(aq) \to CH3COOH(aq)
C) CH3COOH(aq) + HCl(aq) \to CH3COO-(aq) + H2Cl+(aq)
D) 2 CH3COO-(aq) + 2 H+(aq) \to CH3COO(aq) + H2(g)
E) CH3COOH(aq) + H+(aq) \to CH3CO+(aq) + H2O(  What reaction occurs as a hydrochloric acid solution is added to a solution containing equal concentrations of acetic acid and sodium acetate? A) CH<sub>3</sub>COOH(aq) + H<sup>+</sup>(aq)  \to  CH<sub>3</sub>COOH<sub>2</sub><sup>+</sup>(aq)  B) CH<sub>3</sub>COO<sup>-</sup>(aq) + H<sup>+</sup>(aq)  \to   CH<sub>3</sub>COOH(aq)  C) CH<sub>3</sub>COOH(aq) + HCl(aq)  \to  CH<sub>3</sub>COO<sup>-</sup>(aq) + H<sub>2</sub>Cl<sup>+</sup>(aq)  D) 2 CH<sub>3</sub>COO<sup>-</sup>(aq) + 2 H<sup>+</sup>(aq)  \to   CH<sub>3</sub>COO(aq) + H<sub>2</sub>(g)  E) CH<sub>3</sub>COOH(aq) + H<sup>+</sup>(aq)  \to  CH<sub>3</sub>CO<sup>+</sup>(aq) + H<sub>2</sub>O(   )  )

F) A) and B)
G) All of the above

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In the following reaction in aqueous solution,the acid reactant is __________ and its conjugate base product is __________. CH3COOH(aq) + NH3(aq) \leftrightarrows CH3COO-(aq) + NH4+(aq)


A) CH3COOH; CH3COO-
B) CH3COOH; NH4+
C) NH3; CH3COO-
D) NH3; NH4+
E) CH3COOH; H3O+

F) A) and C)
G) C) and E)

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The solubility product for CaF2 is written as __________,where s is the molar solubility.


A) Ksp = s2
B) Ksp = 4s3
C) Ksp = 4s2
D) Ksp = 2s3
E) Ksp = 2s2

F) B) and E)
G) None of the above

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Vitamin C is a monoprotic weak acid,which is also called ascorbic acid (C6H8O5,176 g/mol) .A vitamin C tablet weighing 0.75 g was dissolved in 50.0 mL of water and titrated with 0.250 M sodium hydroxide.It took 12.5 mL of the NaOH solution to reach the end point.What is the percentage of vitamin C in the tablet? Only the vitamin C reacted with the NaOH.


A) 98.7%
B) 64.2%
C) 87.7%
D) 95.5%
E) 73.3%

F) B) and C)
G) A) and B)

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Glycolic acid,which is a monoprotic acid and a constituent in sugarcane,has a pKa of 3.9.A 25.0 mL solution of glycolic acid is titrated to the stoichiometric point with 35.8 mL of 0.020 M sodium hydroxide solution.What is the pH of the resulting solution at the stoichiometric point?


A) 4.12
B) 9.88
C) 6.01
D) 7.99
E) Insufficient information is provided to determine the pH.

F) All of the above
G) C) and E)

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How many moles of sodium acetate must be added to 500.0 mL of 0.250 M acetic acid solution to produce a solution with a pH of 4.94? (The pKa of acetic acid is 4.74.)


A) 0.011 moles
B) 0.021 moles
C) 0.13 moles
D) 0.20 moles
E) 0.21 moles

F) C) and D)
G) All of the above

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Suppose a 1.0 L solution containing 0.20 moles of morphine is titrated with 0.40 M HCl.The pH at the equivalence point is 4.543.What is the Kb of morphine?


A) 1.1 ×\times 10-6
B) 9.4 ×\times 10-9
C) 1.6 ×\times 10-6
D) 6.2 ×\times 10-9
E) Insufficient information is provided to determine Kb.

F) B) and E)
G) B) and C)

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Three acids found in foods are lactic acid (in milk products) ,oxalic acid (in rhubarb) ,and malic acid (in apples) .The pKa values are LA = 3.88,OA = 1.23,and MA = 3.40.Which list has these acids in order of decreasing acid strength?


A) LA > OA > MA
B) LA > MA > OA
C) OA > MA > LA
D) OA > LA > MA
E) MA > LA > OA

F) A) and D)
G) A) and E)

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Which one of the following is NOT a strong base?


A) lithium hydroxide,LiOH
B) sodium hydroxide,NaOH
C) potassium hydroxide,KOH
D) calcium hydroxide,Ca(OH) 2
E) ammonium hydroxide,NH4OH

F) A) and E)
G) A) and B)

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Which of the following statements regarding physiological pH and the carbonic acid-bicarbonate buffer system is NOT correct? CO2(aq) + H2O(  Which of the following statements regarding physiological pH and the carbonic acid-bicarbonate buffer system is NOT correct? CO<sub>2</sub>(aq) + H<sub>2</sub>O(   )  \leftrightarrows   H<sub>2</sub>CO<sub>3</sub>(aq)  \leftrightarrows   H<sup>+</sup>(aq) + HCO<sub>3</sub><sup>-</sup>(aq)  A) The carbonic acid-bicarbonate buffer system regulates the concentration of CO<sub>2</sub> dissolved in blood. B) When the amount of CO<sub>2</sub> dissolved in blood decreases,the pH increases. C) When CO<sub>2</sub> is produced by respiration,the system shifts to the right. D) When acid is added,the system shifts left,which prevents a large pH decrease. E) When base is added,the system shifts right,which prevents a large pH increase. ) \leftrightarrows H2CO3(aq) \leftrightarrows H+(aq) + HCO3-(aq)


A) The carbonic acid-bicarbonate buffer system regulates the concentration of CO2 dissolved in blood.
B) When the amount of CO2 dissolved in blood decreases,the pH increases.
C) When CO2 is produced by respiration,the system shifts to the right.
D) When acid is added,the system shifts left,which prevents a large pH decrease.
E) When base is added,the system shifts right,which prevents a large pH increase.

F) All of the above
G) None of the above

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What is the percent ionization of 0.45 M hydrocyanic acid (HCN,pKa = 9.21)?

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Which of the following lists the conjugate acid of HAsO42- first and its conjugate base second?


A) H3O+; AsO43-
B) AsO43-; H2AsO4-
C) H3AsO4; AsO43-
D) AsO43-;H3AsO4
E) H2AsO4-; AsO43-

F) All of the above
G) A) and D)

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Which sketch best represents the qualitative molecular view of an aqueous solution of nitrous acid? (Water molecules are not shown explicitly.)


A) Which sketch best represents the qualitative molecular view of an aqueous solution of nitrous acid? (Water molecules are not shown explicitly.)  A)    B)    C)    D)    E) none of these
B) Which sketch best represents the qualitative molecular view of an aqueous solution of nitrous acid? (Water molecules are not shown explicitly.)  A)    B)    C)    D)    E) none of these
C) Which sketch best represents the qualitative molecular view of an aqueous solution of nitrous acid? (Water molecules are not shown explicitly.)  A)    B)    C)    D)    E) none of these
D) Which sketch best represents the qualitative molecular view of an aqueous solution of nitrous acid? (Water molecules are not shown explicitly.)  A)    B)    C)    D)    E) none of these
E) none of these

F) A) and E)
G) B) and D)

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When sodium chloride is added to a saturated solution of lead(II) chloride,some of the lead(II) chloride precipitates.This phenomenon is called __________


A) the common-ion effect.
B) selective precipitation.
C) supersaturation.
D) a solubility anomaly.
E) deionization.

F) C) and D)
G) B) and D)

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What is the percent dissociation of 0.150 M triethylamine? (The Kb value for triethylamine is 5.25 ×\times 10-4.)


A) 5.92%
B) 5.75 ×\times 10-3%
C) 39.4%
D) 5.90 ×\times 10-3%
E) 5.75%

F) All of the above
G) C) and E)

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